Alicyclic Chemistry: Volume 4: A Review of Chemical - download pdf or read online

By Royal Society of Chemistry, W. Parker, Parker W

ISBN-10: 0851865828

ISBN-13: 9780851865829

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1974,81,3456); R. C. Gueldner, J. H. Tumlinson, A. C. Thompson, and J. S. P. 3813443 (Chem. , 1974,81, 135545). U. Schmueli and I. , 1974, B30, 573. F. Effenberger and 0. Gerlach, Chem. , 1974, 107, 278; K. R. Berger, E. R. Biehl, and P. C. Reeves, J . Org. , 1974, 39, 477; T. Arimoto and J. Osugi, Chem. Letters, 1974, 271. Three- and Four-membered Rings 49 ethanol, at a rate much faster than either cyclobutane isomer (205; R = Et) opens to (204) in P O E t NC (200) NC NC CN CN WoR OR (203b) NC NC 1 C CN &pN NC CN Use of the methyl ethers (203; R = Me) in ethanol and of the ethyl ethers (203; R = Et) in methanol allows the conformation and reactivity of the intermediate 1,4-dipoles to be examined more closely.

E. Bloor, and J. , p. 4064. R. J. Bailey and H. Shechter, J. Amer. Chem. ,1974,%, 8116. N. Campbell and R. S. S. Perkin I, 1974, 42. C. Eskenad and P. Maitte, Compt. , 1974, 279, C, 233. P. Chaquin, B. Furth, and J. Kossanyi, Compt. , 1974, 279, C, 359. T. R. Darling and C. S. , Amer. Chem. , 1974, 96, 1625; P. J. -C. , p. 5952; P. de Mayo and R. , p. 6807. 45 Three- and Four-membered Rings & dP CO,H \ \ / Ph hv ~ Aq. THF 0 Et OEt I ii, H,O+ p\,,, OH tion. The measurement of Arrhenius activation parameters of hydrogen abstraction in alkylphenyl ketones that the rate enhancements observed in conformationally restricted molecules are entirely entropic in origin.

Thermal and photochemical fragmentations of compound (179) have been examined. Thermolysis results indicated the intermediacy of biradical(l80) but no clear 226 J. R. Garst and J. T. Barbas, J . Amer. ,1974, %, 3239. 227 H. Marschall, K Tantau, and P. , 1974, 107, 887. 228 J. A. Berson, S. S. O h , E. W. , and P. Bickart, Tetrahedron, 1974, 30. 1639. 229 K. R. Kopecky and J. Soler, Canad. J. Chem, 1974,52,211 I . 44 Alicyclic Chemistry t r t tN N I Ph Ph ( I 78a) ( 1 78b) distinction could be made between singlet and triplet possibilities.

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Alicyclic Chemistry: Volume 4: A Review of Chemical Literature (Spr Alicyclic Chemistry (Rsc)) by Royal Society of Chemistry, W. Parker, Parker W

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