Download PDF by Stig Sunner: Combustion Calorimetry. Experimental Chemical Thermodynamics

By Stig Sunner

ISBN-10: 0080209238

ISBN-13: 9780080209234

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18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. , A r m s t r o n g , G . T . J . R e s . N a t . B u r . S t a n d . 1968, 72A, 4 5 3 . , H a r r o p , D . , Head, A . J . , L e w i s , G . B . Chem. T h e r m o d y n a m i c s 1969, 1, 321. W. R e c . T r a v . Chim. 1947, 66, 113. M o s s e l m a n , C , D e k k e r , H. R e c . T r a v . Chim. 1969, 8 8 , 1961 . Hubbard, W . N . , K a t z , C , W a d d i n g t o n , G. J . P h y s . C h e m . 1954, 58, 142. Sunner, S. T h e s i s , U n i v e r s i t y of Lund, S w e d e n .

A counter sums up the n u m b e r of " b e a t s " over a v e r y w e l l d e f i n e d p e r i o d of time a n d displays or p r i n t s the number. After a preset intermission counting starts anew. The advantages are several: measurement and r e c o r d i n g are a u t o m a t i c and the t h e r m o m e t e r g i v e s the a v e r a g e temperature over the counting time interval and thus the timet e m p e r a t u r e i n t e g r a t i o n d u r i n g the m a i n p e r i o d is done by the i n s t r u m e n t .

C o n d u c t i o n as w e l l as c o n v e c t i o n are d e p e n d e n t on t h e p r e s e n c e of i n t e r s p a t i a l m a t t e r , b o t h v a n i s h if a l l m a t t e r i s r e m o v e d . R a d i a t i v e e x c h a n g e i s a l w a y s p r e s e n t a n d n o n - z e r o f o r A T \- 0 . The laws g o v e r n i n g the e x c h a n g e of h e a t are d i f f e r e n t for the three m e c h a n i s m s : radiation follows Stefan-Boltzmann T^-law, c o n d u c t i o n in s t e a d y s t a t e is l i n e a r (directly p r o p o r t i o n a l to A T ) .

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Combustion Calorimetry. Experimental Chemical Thermodynamics by Stig Sunner


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